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Polyphenols and Peroxides: How to Decipher Olive Oil Analyses

Let's learn how to read the lab report for extra virgin olive oil and what peroxide and polyphenol values really mean.

Dipartimento Qualità
February 27, 2026
Upd. Feb 27, 2026
5 min read
Olive Oil Chemistry
Image for Polyphenols and Peroxides: How to Decipher Olive Oil Analyses

1Beyond the Commercial Label

When we come across the chemical analysis report for an olive oil, we find several terms that can seem cryptic. Besides acidity, peroxides and polyphenols stand out.

Peroxides: Oxidation in Progress

The peroxide value (expressed in mEq O₂/kg) indicates oxidative alteration. The law sets the limit at 20 mEq O₂/kg for extra virgin olive oil. An excellent oil is often between 4 and 8.

Polyphenols: The Natural Defense

They are the real treasure of EVOO: they counter oxidation and keep the peroxide level low over time. A high polyphenol value (> 300–400 mg/kg) indicates an oil with a strong sensory character — bitter and spicy — and an extremely long shelf life.

  • < 100 mg/kg: poor oil (industrial, aged)
  • 100–300 mg/kg: commercial standard
  • 300–500 mg/kg: good quality
  • > 500 mg/kg: absolute excellence

Always ask your producer for the lab results — a good olive mill will be happy to provide them.